Roy Bacon's Twin Restoration lists final drive as 0.625 x 0.0400 x 0.380", 99 pitches for 1962/1963. Page 215/1986 Edition.
Narrower chains were fitted to lower powered ranges, sprocket fittings and dimensions are the same, so an element of mis-match and swaps is possible.
If this sprocket came off a running bike, the gearbox sprocket will be wrong for the model as well, again narrower teeth to fit the chain.
Gold Star used 5/8 x 1/4 until 1958, then moving to 5/8 x 3/8. Roy Bacon again, "Gold Star and other Singles". 1985/p146.
So it could actually be an early Gold Star transmission, but not strictly correct for a more powerful machine.
Swarfy.